<asp:GridView ID="GV" runat="server" AutoGenerateColumns="False">
<Columns>
<asp:HyperLinkField DataNavigateUrlFields="CAM,Floor,Riser" DataNavigateUrlFormatString="HorzHandover.aspx?CAM={0}&Floor={1}&Riser={2}" Text="Handover"/>
<asp:TemplateField>
<ItemTemplate>
<asp:HyperLink ID="HyperLink1" runat="server" NavigateUrl='<%# "Export.aspx?CAM="+Eval("CAM")+"&Floor="+Eval("Floor")+"&Riser="+Eval("Riser") %>' Text="Signoff"></asp:HyperLink> </ItemTemplate>
</asp:TemplateField>
</Columns>
</asp:GridView>
I think this is a bug in asp.net. HyperLinkField in GridViews with multiple fields do not seem to work at all. You have to turn column into a template to make it work (as shown above)